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CC(C)(C)[Si](C)(C)OC[C@]12CCC(=O)C=C1CC[C@@H]1[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]12
Reaction #459008
19-t-butyldimethylsiloxy-4-androstene-3,17-dione
DOI: 10.6084/m9.figshare.5104873.v1
C[C@H]1C[C@@H]2[C@H](CC[C@]3(C)C(=O)CC[C@@H]23)[C@@]2(CO[Si](C)(C)C(C)(C)C)CCC(=O)C=C12
Reaction #459009
19-t-butyldimethylsiloxy-6α-methyl-4-androstene-3,17-dione
DOI: 10.6084/m9.figshare.5104873.v1
CC(C)(C)[Si](C)(C)OCCO[C@H]1CC[C@@]2(C)C(=CC[C@@H]3[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]32)C1
Reaction #527902
3β-(2-tert-butyldimethylsilyloxyethoxy)-androst-5-en-17-one
Ausbeute 93.0%DOI: 10.6084/m9.figshare.5104873.v1
COC[C@]12CCC(=O)CC1=CC[C@@H]1[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]12
Reaction #1477943
19-methoxyandrost-5-ene-3,17-dione
DOI: 10.6084/m9.figshare.5104873.v1
COC[C@]12CC[C@H](O)CC1=CC[C@@H]1[C@@H]2CC[C@]2(C)[C@@H](O)CC[C@@H]12
Reaction #1477944
19-methoxyandrost-5-ene-3β,17β-diol
DOI: 10.6084/m9.figshare.5104873.v1
CC(C)(C)[Si](C)(C)OC[C@]12CCC(=O)C=C1CC[C@@H]1[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]12
Reaction #1477949
19-t-butyldimethylsiloxy-4-androstene-3,17-dione
DOI: 10.6084/m9.figshare.5104873.v1
CC(=O)O.CC(C)(C)[Si](C)(C)OC1CC[C@@]2(CO)C(=CC[C@@H]3[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]32)C1
Reaction #1477950
3-t-butyldimethylsiloxy-19-hydroxy-5-androsten-17-one acetate
DOI: 10.6084/m9.figshare.5104873.v1
CC(C)(C)[Si](C)(C)OC[C@]12CCC(=O)CC1=CC[C@@H]1[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]12
Reaction #1477951
19-t-butyldimethylsiloxy-5-androstene-3,17-dione
DOI: 10.6084/m9.figshare.5104873.v1
CC1=C2CC(=O)CC[C@]2(CO[Si](C)(C)C(C)(C)C)[C@H]2CC[C@]3(C)C(=O)CC[C@H]3[C@@H]2C1
Reaction #1477952
19-t-butyldimethylsiloxy-6-methyl-5-androstene-3,17-dione
DOI: 10.6084/m9.figshare.5104873.v1
CC(C)(C)[Si](C)(C)OC[C@]12CC[C@@H](O)CC1=CC[C@@H]1[C@@H]2CC[C@]2(C)C(O)CC[C@@H]12
Reaction #1477954
19-t-butyldimethylsiloxy-5-androstene-3α,17-diol
DOI: 10.6084/m9.figshare.5104873.v1
C[C@]12CC[C@H]3[C@@H](CC=C4CC(=O)CC[C@@]43CO[Si](C)(C)C)[C@@H]1CCC2=O
Reaction #1477960
19-trimethylsiloxy-5-androstene-3,17-dione
DOI: 10.6084/m9.figshare.5104873.v1
CC1=C2CC(=O)CC[C@]2(CO[Si](C)(C)C)[C@H]2CC[C@]3(C)C(=O)CC[C@H]3[C@@H]2C1
Reaction #1477961
6-methyl-19-trimethylsiloxy-5-androstene-3,17-dione
DOI: 10.6084/m9.figshare.5104873.v1
C[C@]12CC[C@H]3[C@@H](CC=C4C[C@@H](O)CC[C@@]43CO[Si](C)(C)C)[C@@H]1CC[C@@H]2O
Reaction #1477962
19-trimethylsiloxy-5-androstene-3β,17β-diol
DOI: 10.6084/m9.figshare.5104873.v1
CC(C)(C)[Si](C)(C)OC[C@]12CCC(=O)C=C1CC[C@@H]1[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]12
Reaction #1820268
19-t-butyldimethylsiloxy-4-androstene-3,17-dione
DOI: 10.6084/m9.figshare.5104873.v1
C[C@H]1C[C@@H]2[C@H](CC[C@]3(C)C(=O)CC[C@@H]23)[C@@]2(CO[Si](C)(C)C(C)(C)C)CCC(=O)C=C12
Reaction #1820269
19-t-butyldimethylsiloxy-6α-methyl-4-androstene-3,17-dione
DOI: 10.6084/m9.figshare.5104873.v1
CC12CCC3C(CC=C4CC(=O)CCC43CO[Si](C)(C)C)C1CCC2=O
Reaction #2221314
DOI: 10.1039/C8SC04228D