تفاعل #997152

معادلة التفاعل

sodium 2-(1-adamantanecarbonyloxy)-1,1-difluoro-ethanesulfonate

triphenylsulfonium chloride

→

compound

المردود 85.0%

triphenylsulfonium 2-(1-adamantanecarbonyl-oxy)-1,1-difluoroethanesulfonate

المردود 85.0%

المذيبات

dichloromethane

ظروف التفاعل

المعالجة

1. 1
   أخرىThe organic layer was separated
2. 2
   غسيلwashed three times with 20 g of water
3. 3
   تركيزconcentrated
4. 4
   workup.ADDITIONDiethyl ether was added to the residue for recrystallization

الإجراء التجريبي

In 100 g of dichloromethane were dissolved 10 g (0.02 mole) of sodium 2-(1-adamantanecarbonyloxy)-1,1-difluoro-ethanesulfonate (purity 70%) and 50 g (0.02 mole) of a triphenylsulfonium chloride aqueous solution. The organic layer was separated, washed three times with 20 g of water, and concentrated. Diethyl ether was added to the residue for recrystallization, obtaining the target compound as white crystals. 10 g (yield 85%).

المصدر