تفاعل #985327

ord-f07cb4c8e2b444a2ad2eedeaf712b641

معادلة التفاعل

CNC(=O)Cn1cc(C(=O)C(F)(F)F)c2ccc(Cl)cc21
2-[6-Chloro-3-(2,2,2-trifluoro-acetyl)-indol-1-yl]-N-methyl-acetamide
C[Si](C)(C)[O-].[Na+]
sodium trimethylsilanolate
CNC(=O)Cn1cc(C(=O)O)c2ccc(Cl)cc21
title compound
CNC(=O)Cn1cc(C(=O)O)c2ccc(Cl)cc21
6-Chloro-1-methylcarbamoylmethyl-1H-indole-3-carboxylic acid

المذيبات

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    تركيزthe mixture was concentrated in vacuo
  2. 2
    أخرىpurified by prep

الإجراء التجريبي

2-[6-Chloro-3-(2,2,2-trifluoro-acetyl)-indol-1-yl]-N-methyl-acetamide was suspended in DCE and treated with (2.2 eq.) of sodium trimethylsilanolate. After shaking at room temperature for 20 min, the mixture was concentrated in vacuo and purified by prep. HPLC to give the title compound.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US07351706B2uspto-grants-2008_04