تفاعل #985272
ord-824fe9bba7f942c1a87460fd109fcf84
معادلة التفاعل
diethyl azodicarboxylate
5,5,6,6,7,7,8,8,8-nonafluorooctan-1-ol
4-bromophenol
triphenylphosphine
→
4-Bromo-1-(5,5,6,6,7,7,8,8,8-nonafluorooctyloxy)benzene
المتفاعلات
الكواشف
لا شيء
المذيبات
ظروف التفاعل
الظروف التفصيلية
See reaction.notes.procedure_details.
الإجراء التجريبي
A solution of diethyl azodicarboxylate (3.5 g, 20 mmol) in dry diethyl ether (20 cm3) was added dropwise into a stirred solution of 5,5,6,6,7,7,8,8,8-nonafluorooctan-1-ol (Preparation 2A, 5.8 g, 20 mmol), 4-bromophenol (3.5 g, 20 mmol) and triphenylphosphine (5.3 g, 20 mmol) in dry diethyl ether (50 cm3) at room temperature.