تفاعل #95982

معادلة التفاعل

5-Benzylthio-2-(1H-tetrazole-5-ylmethyl)-2H-tetrazole

→

2-(1H-Tetrazole-5-ylmethyl)-2H-tetrazole-5-thiol

المذيبات

DMF

ظروف التفاعل

المعالجة

1. 1
   أخرى, prepared
2. 2
   workup.DISSOLUTIONwas dissolved in 40 ml
3. 3
   أخرىThe electrodes were separated by a glass frit
4. 4
   workup.WAITfor about 630 seconds

الإجراء التجريبي

5-Benzylthio-2-(1H-tetrazole-5-ylmethyl)-2H-tetrazole, 175 mg., prepared as described above under part C, was dissolved in 40 ml. of distilled DMF and reduced at the mercury pool cathode (14 cm2Hg pool) with a platinium wire anode. The electrodes were separated by a glass frit. The electrolyte was tetraethylammonium perchlorate, 0.1 M in the DMF solution of the substrate. The electrolysis was carried out at -2.7 to -2.85 volts for 500 seconds at -2.80 v. for about 630 seconds.

المصدر