تفاعل #955949

معادلة التفاعل

9-(Bromomethyl)phenanthrene

triethyl phosphite

→

product

المردود 56.8%

diethyl (phenanthren-9-ylmethyl)phosphonate

المردود 56.8%

ظروف التفاعل

المعالجة

1. 1
   تركيزThe reaction mixture was concentrated
2. 2
   أخرىthe residue was purified by silica gel column chromatography

الإجراء التجريبي

9-(Bromomethyl)phenanthrene (18 g, 66.4 mmol) and triethyl phosphite (10.7 g) were mixed and heated to 150° C. under N2 for 4 h. The reaction mixture was concentrated and the residue was purified by silica gel column chromatography to yield 12 g of product.

المصدر