تفاعل #95320

معادلة التفاعل

hydrogen peroxide

tetrachloroacetone

cyclooctene

chloroform

→

cyclooctene oxide

المردود 83.0%

المذيبات

water

ظروف التفاعل

المعالجة

1. 1
   أخرىWater was removed continuously as it
2. 2
   أخرىwas formed, over a period of 4 hours
3. 3
   درجة الحرارةof heating
4. 4
   أخرىThe organic phase was then separated from the aqueous phase

الإجراء التجريبي

There were added 13.68 parts of a 50% aqueous hydrogen peroxide to a refluxing mixture of 3.92 parts of tetrachloroacetone, 11.58 parts of cyclooctene and 149 parts of chloroform. Water was removed continuously as it was formed, over a period of 4 hours of heating. The removed water was then added to the reaction mixture. The organic phase was then separated from the aqueous phase. Based on VPC analysis there was obtained an 83% yield of cyclooctene oxide.

المصدر