تفاعل #950

معادلة التفاعل

triphenylphosphine

3,3,3-trifluoropropyl iodid

→

solid

المردود 76.5%

(3,3,3-Trifluoropropyl)triphenylphosphonium iodide

المردود 76.5%

المذيبات

ظروف التفاعل

المعالجة

1. 1
   أخرىThe solid which formed
2. 2
   ترشيحwas filtered
3. 3
   غسيلwashed with xylenes
4. 4
   أخرىair dried

الإجراء التجريبي

A solution of triphenylphosphine (Aldrich, 11.7 g) and 3,3,3-trifluoropropyl iodid (Lancaster, 10 g) was vigorously refluxed in xylenes (75 mL) for 2 days. The solid which formed was filtered and washed with xylenes then air dried to yield a white solid (16.6 g). 1H NMR and elemental analysis are consistent with the proposed structure.

المصدر