تفاعل #94895

معادلة التفاعل

3-phenyl-3-(4-nitrophenyl)propenoic acid

thionyl chloride

→

3-Phenyl-3-(4-nitrophenyl)propenoyl chloride

المذيبات

benzene

ظروف التفاعل

المعالجة

1. 1
   workup.ADDITIONA mixture of 22 g
2. 2
   درجة الحرارةunder reflux for 1 hour
3. 3
   أخرىThe solvent was removed by evaporation in vacuo
4. 4
   أخرىthe residual solid was recrystallized from carbon tetrachloride

الإجراء التجريبي

A mixture of 22 g. of 3-phenyl-3-(4-nitrophenyl)propenoic acid, 11.7 g. of thionyl chloride and 150 ml. of benzene was heated under reflux for 1 hour. The solvent was removed by evaporation in vacuo, and the residual solid was recrystallized from carbon tetrachloride. This afforded 20 g. of the title compound, m.p. 117°-120° C.

المصدر