تفاعل #94254

معادلة التفاعل

cyclohexyl isocyanate

1,3-dimethyl-3-hydroperoxybutyl alcohol

→

colorless solid

المردود 39.0%

1,3-Dimethyl-3-(N-cyclohexyl-carbamoylperoxy)butyl N-cyclohexylcarbamate

المردود 39.0%

المذيبات

ether

ظروف التفاعل

المعالجة

1. 1
   workup.ADDITIONA mixture of 18.7 g
2. 2
   أخرىThe reaction vessel was protected with a calcium chloride tube
3. 3
   ترشيحfiltered
4. 4
   غسيلThe filter cake was washed with an additional 30 ml of ether and air
5. 5
   أخرىdried

الإجراء التجريبي

A mixture of 18.7 g. (0.15 mole) of cyclohexyl isocyanate, 6.7 g. (0.05 mole) of 1,3-dimethyl-3-hydroperoxybutyl alcohol and 3 drops of triethylamine was stirred for 5 days at ambient temperature. The reaction vessel was protected with a calcium chloride tube to keep out moisture. Within 2 days, a solid began to appear, and after the 5 day stirring period the reaction mixture was stripped in vacuo. The residue was slurried in 100 ml of ether and filtered. The filter cake was washed with an additional 30 ml of ether and air dried. A total of 7.5 grams of a colorless solid was obtained.

المصدر