تفاعل #927678

ord-f453fa0f25164914b5f276ce420bb989

معادلة التفاعل

O=C1C=CC(=O)O1
maleic anhydride
CCC(CC)(CO)COC(=O)C1C2C=CC(C2)C1C(=O)[O-]
mono-2-ethyl-2-(hydroxymethyl)butyl bicyclo-[2.2.1]hept-5-ene-2,3-dicarboxylate
CC(C)(C)OC(=O)C1CC2C=CC1C2
tert-butyl bicyclo-[2.2.1]hept-5-ene-2-carboxylate
C=C(C)C(=O)OCCC[Si](O[Si](C)(C)C)(O[Si](C)(C)C)O[Si](C)(C)C
3-[tris(trimethylsiloxy)silyl]propyl methacrylate
CC(C)(C#N)N=NC(C)(C)C#N
AIBN
→
C=C(C)C(=O)OCCC[Si](O[Si](C)(C)C)(O[Si](C)(C)C)O[Si](C)(C)C.CC(C)(C)OC(=O)C1CC2C=CC1C2.CCC(CC)(CO)COC(=O)C1C2C=CC(C2)C1C(=O)[O-].O=C1C=CC(=O)O1
maleic anhydride mono-2-ethyl-2-(hydroxymethyl)butyl bicyclo[2.2.1]hept-5-ene-2.3-dicarboxylate tert-butyl bicyclo-[2.2.1]hept-5-ene-2-carboxylate 3-[tris(trimethylsiloxy)silyl]propyl methacrylate

المتفاعلات

O=C1C=CC(=O)O1
maleic anhydride
CCC(CC)(CO)COC(=O)C1C2C=CC(C2)C1C(=O)[O-]
mono-2-ethyl-2-(hydroxymethyl)butyl bicyclo-[2.2.1]hept-5-ene-2,3-dicarboxylate
CC(C)(C)OC(=O)C1CC2C=CC1C2
tert-butyl bicyclo-[2.2.1]hept-5-ene-2-carboxylate
C=C(C)C(=O)OCCC[Si](O[Si](C)(C)C)(O[Si](C)(C)C)O[Si](C)(C)C
3-[tris(trimethylsiloxy)silyl]propyl methacrylate
—
resultant mixture
CC(C)(C#N)N=NC(C)(C)C#N
AIBN

الكواشف

لا شيء

المذيبات

C1CCOC1
tetrahydrofuran

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

الإجراء التجريبي

1.0 mole of maleic anhydride, 0.2 mole of mono-2-ethyl-2-(hydroxymethyl)butyl bicyclo-[2.2.1]hept-5-ene-2,3-dicarboxylate, 0.7 mole of tert-butyl bicyclo-[2.2.1]hept-5-ene-2-carboxylate and 0.1 mole of 3-[tris(trimethylsiloxy)silyl]propyl methacrylate are dissolved in tetrahydrofuran, 0.5 to 10 g of AIBN is added thereto as the polymerization initiator, and the resultant mixture is reacted at approximately 60 to 70° C. for 4 to 24 hours under a nitrogen or argon atmosphere.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US06368771B1uspto-grants-2002_04