تفاعل #82143

معادلة التفاعل

N-Allylphenylamine

bromopentane

sodium hydroxide

→

N-allyl-N-pentylphenylamine

المردود 56.2%

المذيبات

water

ظروف التفاعل

المعالجة

1. 1
   استخلاصextracted with ether (80 ml)
2. 2
   تجفيفThe extract was dried over potassium carbonate, filterd
3. 3
   تركيزconcentrated in vacuum
4. 4
   أخرىThe residue was chromatographed on silica gel

الإجراء التجريبي

N-Allylphenylamine (1.95 g, 14.7 mmol) and bromopentane (2.22 g, 14.7 mmol) were stirred at 80° C. for 16 hours. After cooled to room temperature, the mixture was treated with a solution of sodium hydroxide(714 mg, 17.9 mmol) in water (1.5 ml), stirred for 30 minutes and extracted with ether (80 ml). The extract was dried over potassium carbonate, filterd and concentrated in vacuum. The residue was chromatographed on silica gel to give N-allyl-N-pentylphenylamine (1.68 g) in 56% yield as a colorless oil.

المصدر