تفاعل #816409

ord-ee5995cd94bf437e8322f173728ed95e

معادلة التفاعل

[Cd+2].[O-2]
Cadmium oxide
CCCCCCCCCCCCCCC(=O)O
tetradecyl carboxylic acid
CCCCCCCCCCCCCCC(=O)[O-].CCCCCCCCCCCCCCC(=O)[O-].[Cd+2]
cadmium tetradecylcarboxylate

الكواشف

لا شيء

ظروف التفاعل

درجة الحرارة
90°CELSIUS
الظروف التفصيلية
See reaction.notes.procedure_details.

الإجراء التجريبي

Cadmium oxide (0.127 g, 1 mmol) and tetradecyl carboxylic acid (0.500 g) were reacted at 220° C. for 10 min, cooled to 90° C., a cadmium tetradecylcarboxylate (precursor) was formed. Into said system, toluene (10 ml) and mercapto-etanol (0.6 ml) was added. Then a 0.05M aqueous solution of sodium hydrogen selenide (10 ml) was added. After the system was reacted at 90° C. for 3 h, a red sol containing the mercaptoethanol-coated CdSe nanoparticles was obtained. Said sol can be dispersed stably in water, has a typical exciton absorption peak of the CdSe nanoparticles, can result in a quantum size effect and emit a fairly strong green light under the irradiation of a UV lamp.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US07582543B2uspto-grants-2009_09