تفاعل #78410

ord-ed221a40b0554bbd900e864b34ebf7eb

معادلة التفاعل

C=CC(=O)[O-]
acrylate
C1=CCC=C1
cyclopentadiene
Cc1ccccc1
toluene
C1=CC2C3C=CC(C3)C2C1
Dicyclopentadiene

المتفاعلات

الكواشف

لا شيء

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    أخرىThe derivative was synthesized
  2. 2
    درجة الحرارةcooled with ice

الإجراء التجريبي

The derivative was synthesized as follows. 20 grams of the derivative of acrylate obtained as the third example was dissolved in 20 milliliters of toluene. 7 grams of cyclopentadiene was dropped into the solution cooled with ice, and was agitated through all night. Dicyclopentadiene was produced as by-product, and was eliminated in vacuum. Then, 24.9 grams of the derivative of norbornene was obtained. The derivative of norbornene was viscous liquid, and the yield was 95%.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US06710188B2uspto-grants-2004_03