تفاعل #77935

معادلة التفاعل

5-nitro-1-naphthylamine

hydrogen

→

1,5-naphthalenediamine

المردود 97.5%

المذيبات

toluene

ظروف التفاعل

المعالجة

1. 1
   أخرىOn completion of the reaction
2. 2
   ترشيحthe catalyst is filtered off

الإجراء التجريبي

8.20 g of 5-nitro-1-naphthylamine (43.6 mmol) in 35 ml of toluene are placed in a 0.1 liter autoclave with 0.5 g of palladium on carbon (5%) and hydrogenated at 50° C. and 40 bar hydrogen pressure for 5 h, stirring. On completion of the reaction, the cooled autoclave is depressurised and the catalyst is filtered off. With a quantitative conversion, 6.72 g of 1,5-naphthalenediamine (42.5 mmol, 97.5%) are formed.

المصدر