تفاعل #75419

ord-0410bd88a01c4582b44e3ebdf4e24ed1

معادلة التفاعل

N[C@@H](CC1(C(=O)C(CS)CS)C=CC=CC1)C(=O)O
1-[2-(mercaptomethyl)-3-mercaptopropanoyl]-L-phenylalanine
N[C@@H](Cc1ccccc1)C(=O)O
L-phenylalanine
O=C(O)[C@@H]1CCCN1
L-proline
N[C@@H](Cc1ccccc1)C(=O)O
L-phenylalanine
→
O=C(N[C@@H](Cc1ccccc1)C(=O)O)C(CS)CS
N-[2-(Mercaptomethyl)-3-mercaptopropanoyl]-L-phenylalanine

المتفاعلات

N[C@@H](CC1(C(=O)C(CS)CS)C=CC=CC1)C(=O)O
1-[2-(mercaptomethyl)-3-mercaptopropanoyl]-L-phenylalanine
N[C@@H](Cc1ccccc1)C(=O)O
L-phenylalanine
O=C(O)[C@@H]1CCCN1
L-proline
N[C@@H](Cc1ccccc1)C(=O)O
L-phenylalanine

الكواشف

لا شيء

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    أخرىare obtained

الإجراء التجريبي

By substituting L-phenylalanine for the L-proline in the procedure of Example 3B, and then submitting the product to the procedure of Example 4, 1-[2-acetylthiomethyl)-3-acetylthiopropanoyl]-L-phenylalanine and 1-[2-(mercaptomethyl)-3-mercaptopropanoyl]-L-phenylalanine are obtained.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US04176235uspto-grants-1979_11