تفاعل #75020

ord-3382055977444d27a94c974baede3424

معادلة التفاعل

C=Cc1ccccc1
Styrene
CC(=O)O
acetic acid
O=C1CCC(c2ccccc2)O1
gamma-phenyl butyrolactone
المردود 70.0%

الكواشف

لا شيء

ظروف التفاعل

درجة الحرارة
110°CELSIUS
الظروف التفصيلية
See reaction.notes.procedure_details.

الإجراء التجريبي

Styrene in the amount of 20 grams was dissolved in 100 milliliters of acetic acid containing 10% potassium acetate. Ceric acetate in the amount of 0.005 mole was added and the reaction mixture was heated in a sealed tube at 110° C. overnight. The lactone, gamma-phenyl butyrolactone, was obtained in 70% yield.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US04175089uspto-grants-1979_11