تفاعل #74963

معادلة التفاعل

Hexachlorocyclopentadiene

tert-butyl-p-benzoquinone

→

6-tert-butyl-1,2,3,4,9,9-hexachloro-1,4,4a,8a-tetrahydro-1,4methanonaphthalene-5,8-dione

المذيبات

toluene

ظروف التفاعل

المعالجة

1. 1
   غسيلThe solid was washed with methanol
2. 2
   أخرىrecrystallized from benzene
3. 3
   أخرىYellow crystals were obtained melting at 124°-125° C.

الإجراء التجريبي

Hexachlorocyclopentadiene, 40 g., and 15.4 g. of tert-butyl-p-benzoquinone were dissolved in 300 ml. of toluene and refluxed for four hours. The solution solidified upon cooling to room temperature. The solid was washed with methanol and recrystallized from benzene. Yellow crystals were obtained melting at 124°-125° C.

المصدر