تفاعل #71585

ord-9a99f6c83ecb45f2a14080de6416e4b9

معادلة التفاعل

C/C=C(\C)C(=O)OCC
ethyl tiglate
CC(O)=S
thioacetic acid
C/C=C(\C)C(=O)OCC
ethyl tiglate
CCOC(=O)C(C)C(C)SC(C)=O
ethyl 3-acetylthio-2-methylbutyrate

الكواشف

لا شيء

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    أخرىwas prepared
  2. 2
    أخرىto react under nitrogen atmosphere at 85° C. for 24 hours

الإجراء التجريبي

A mixture of 3.20 g (0.025 mol) of ethyl tiglate and 4.76 g (0.0625 mol) of thioacetic acid was prepared and allowed to react under nitrogen atmosphere at 85° C. for 24 hours. The results showed that the conversion rate of ethyl tiglate was 35.3%, and that the selectivity for the objective compound was 91.6%.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US08536364B2uspto-grants-2013_09