تفاعل #696695

معادلة التفاعل

1,4-diaminobutane

triethylamine

2-chloro-2-methyl-3-nitrosopentane

→

2-(4-aminobutyl)amino-2-methyl-3-pentanone oxime

المذيبات

acetonitrile

acetonitrile

ظروف التفاعل

المعالجة

1. 1
   أخرىto precipitate
2. 2
   workup.STIRRINGThe reaction mixture was stirred overnight
3. 3
   ترشيحthe product was filtered off
4. 4
   أخرىdried in vacuo
5. 5
   أخرىto give a white powder, (0.5 g; 86%)

الإجراء التجريبي

To a stirred solution of 1,4-diaminobutane (0.26 g; 2.9 mmol) and triethylamine (0.33 g; 3.2 mmol) in acetonitrile (5 ml) was added a solution of 2-chloro-2-methyl-3-nitrosopentane (0.485 g; 3.24 mmol) in acetonitrile (5 ml). After stirring for ca 10 minutes the product began to precipitate. The reaction mixture was stirred overnight and the product was filtered off and dried in vacuo to give a white powder, (0.5 g; 86%).

المصدر