تفاعل #695080

ord-9b0ea48244fd41668f9af3646ee60cf3

معادلة التفاعل

→

$C1=C\CC/C=C\CC/1.C1=C\CC/C=C\CC/1.[Ni]$

درجة الحرارة

60°CELSIUS

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workup.ADDITIONDilute with acetonitrile
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workup.ALIQUOT
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أخرىDiluent solution was made in 1 L batches with 950 mL acetonitrile, 25 mL water, 25 mL glacial acetic acid, and 53 mg 4,4’-di-tert-butylbiphenyl as an external standard (0.2 equiv standard per reaction). Aliquot taken from each well (47 ul) is added into 753 ul of diluent solution

pre-ligate Ni(cod)2 and phosphine ligand in dioxane for 15 minutes in a separate plate

DOI: 10.26434/chemrxiv.14388557.v1Ni-catalyzed Suzuki Miyaura cross-coupling