تفاعل #68704

ord-2249a546e80243079730b7f18d3febb6

معادلة التفاعل

CC[P+](CC)(c1ccccc1)c1ccccc1.[I-]
diphenyldiethylphosphonium iodide
[OH-]
hydroxide
CC[P+](CC)(c1ccccc1)c1ccccc1.[OH-]
diphenyldiethylphosphonium hydroxide
المردود 96.0%

الكواشف

لا شيء

المذيبات

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

الإجراء التجريبي

This 98.45 g of diphenyldiethylphosphonium iodide was then dissolved in water, and converted to the corresponding hydroxide with 270 g of an anionic exchange resin in batch overnight, yielding 271.75 g of a 0.94 M solution of diphenyldiethylphosphonium hydroxide (96% of exchange yield) The diphenyldiethylphosphonium hydroxide was used as SDA source.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US08529868B2uspto-grants-2013_09