تفاعل #658302

معادلة التفاعل

N-t-butyldimethylsilyl-N-benzyl-N-allylamine

trimethoxysilane

→

N-t-butyldimethylsilyl-N-benzyl-3-aminopropyltrimethoxysilane

المذيبات

toluene

ظروف التفاعل

المعالجة

1. 1
   أخرىA flask equipped with a stirrer
2. 2
   درجة الحرارةreflux condenser
3. 3
   workup.DISTILLATIONThe reaction solution was distilled
4. 4
   أخرىcollecting 32.6 g of a fraction

الإجراء التجريبي

A flask equipped with a stirrer, reflux condenser, dropping funnel and thermometer was charged with 26.2 g (0.1 mol) of N-t-butyldimethylsilyl-N-benzyl-N-allylamine and 0.07 g of a toluene solution of platinum/1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex (Pt concentration 3 wt %) and heated at 50° C. Once the internal temperature became steady, 12.2 g (0.1 mol) of trimethoxysilane was added dropwise over 1 hour. Stirring was continued at the temperature for a further 1 hour. The reaction solution was distilled, collecting 32.6 g of a fraction having a boiling point of 165-166° C./0.4 kPa.

المصدر