تفاعل #64064

ord-5eb06e7eed3f4943999d3ac847ea7b64

معادلة التفاعل

CCCC(=O)C1=C(O)CC(c2c(C)c(C)c(C)c(C)c2S(C)(=O)=O)CC1=O
2-butyryl-3-hydroxy-5-(6-methylsulfonyl-2,3,4,5-tetramethylphenyl)cyclohex-2-en-1-one
CCON.Cl
ethoxyamine hydrochloride
→
CCCC(=NOCC)C1=C(O)CC(c2c(C)c(C)c(C)c(C)c2S(C)(=O)=O)CC1=O
2-[1-(Ethoxyimino)butyl]-3-hydroxy-5-(6-methylsulfonyl-2,3,4,5-tetramethylphenyl)cyclohex-2-en-1-one

المتفاعلات

CCCC(=O)C1=C(O)CC(c2c(C)c(C)c(C)c(C)c2S(C)(=O)=O)CC1=O
2-butyryl-3-hydroxy-5-(6-methylsulfonyl-2,3,4,5-tetramethylphenyl)cyclohex-2-en-1-one
CCON.Cl
ethoxyamine hydrochloride
—
( iv )

الكواشف

لا شيء

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

الإجراء التجريبي

2-[1-(Ethoxyimino)butyl]-3-hydroxy-5-(6-methylsulfonyl-2,3,4,5-tetramethylphenyl)cyclohex-2-en-1-one (57) was prepared from 2-butyryl-3-hydroxy-5-(6-methylsulfonyl-2,3,4,5-tetramethylphenyl)cyclohex-2-en-1-one and ethoxyamine hydrochloride following essentially the same procedure as that described in Example 1, part (iv). The product was characterized by proton nuclear magnetic resonance spectroscopy and the spectroscopic data is reported in Table 5, Example 37.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US04767879uspto-grants-1988_08