تفاعل #631971

ord-43b48e2ce5cd45609b530a2602e1348d

معادلة التفاعل

C=CC(=O)OCCC(=O)O
2-Carboxyethyl acrylate
O=S(Cl)Cl
Thionyl chloride
C=CC(=O)OCCC(=O)Cl
desired product
C=CC(=O)OCCC(=O)Cl
3-chloro-3-oxopropyl acrylate

الكواشف

لا شيء

المذيبات

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    درجة الحرارةthe solution is cooled in an ice bath
  2. 2
    أخرىThe solvent is removed under reduced pressure

الإجراء التجريبي

2-Carboxyethyl acrylate (1 eq.) is dissolved in CH2Cl2 and the solution is cooled in an ice bath. Thionyl chloride (1 eq.) is added dropwise and the mixture is allowed to warm to room temperature and stir for 4 hours. The solvent is removed under reduced pressure and the desired product is isolated by vacuum distillation.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US07935131B2uspto-grants-2011_05