تفاعل #63093

ord-7214a9f8f68b469d8b052d0ae456dbe1

معادلة التفاعل

NC(=NCC(F)(F)F)Nc1nc(CCCCN=C=S)cs1
2-[2-(2,2,2-trifluoroethyl)guanidino]-4-(4-isothiocyanatobutyl)thiazole
Nc1ccccc1N
o-phenylenediamine
NC(=NCC(F)(F)F)Nc1nc(CCCCNC(=S)Nc2ccccc2N)cs1
2-[2-(2,2,2-trifluoroethyl)guanidino]-4-[4-(3-[2-aminophenyl]thioureido)butyl]thiazole

المذيبات

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    درجة الحرارةwas heated
  2. 2
    درجة الحرارةunder reflux for 2 hours
  3. 3
    أخرىEvaporation of the reaction mixture to dryness

الإجراء التجريبي

A mixture of 2-[2-(2,2,2-trifluoroethyl)guanidino]-4-(4-isothiocyanatobutyl)thiazole (0.33 g.) and o-phenylenediamine in alcohol (5 ml.) was heated under reflux for 2 hours. Evaporation of the reaction mixture to dryness gave 2-[2-(2,2,2-trifluoroethyl)guanidino]-4-[4-(3-[2-aminophenyl]thioureido)butyl]thiazole as an oil which was used without further purification.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US04762932uspto-grants-1988_08