تفاعل #548706

معادلة التفاعل

polyethylene

acetone cyclohexylhydrazone

oxygen

→

2-Cyclohexylazo-2-Hydroperoxypropane

المردود 85.0%

المذيبات

heptane

ظروف التفاعل

المعالجة

1. 1
   أخرىwas initiated at 35° C
2. 2
   درجة الحرارةThe solution was cooled to 0°
3. 3
   درجة الحرارةcooled
4. 4
   أخرىstored at -30° C

الإجراء التجريبي

A solution of 5.0 grams (0.0324 moles) of acetone cyclohexylhydrazone in 70 grams of heptane was oxidized by passing oxygen through the solution as in Example II. The oxidation was initiated at 35° C. The reaction was followed by gas chromatography, following the disappearance of the cyclohexylhydrazone peak. The reaction was complete in 35 minutes at 35° C. The solution was cooled to 0° and drained into a tared, cooled, polyethylene bottle, weighed and stored at -30° C. The solution weighed 75.1 grams (85% yield).

المصدر