تفاعل #511510

ord-fca1f023a26f43d79666ab4e83aa1f14

معادلة التفاعل

CC(C)(C)c1ccc(S(=O)c2ccc(C(C)(C)C)cc2)cc1
bis(4-tert-butylphenyl) sulfoxide
CC(C)(C)c1ccc(Br)cc1
4-tert-butylbromobenzene
→
CC(C)(C)c1ccc([S+](c2ccc(C(C)(C)C)cc2)c2ccc(C(C)(C)C)cc2)cc1.[Br-]
tris(4-tert-butylphenyl)sulfonium bromide

المتفاعلات

CC(C)(C)c1ccc(S(=O)c2ccc(C(C)(C)C)cc2)cc1
bis(4-tert-butylphenyl) sulfoxide
CC(C)(C)c1ccc(Br)cc1
4-tert-butylbromobenzene

الكواشف

لا شيء

المذيبات

O
water

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    أخرىThe target compound was obtained
  2. 2
    أخرىthe procedure of Synthesis Example 1-1 aside
  3. 3
    أخرىin Synthesis Example 1-1
  4. 4
    استخلاصfor extraction

الإجراء التجريبي

The target compound was obtained by following the procedure of Synthesis Example 1-1 aside from using bis(4-tert-butylphenyl) sulfoxide instead of the diphenyl sulfoxide and 4-tert-butylbromobenzene instead of the chlorobenzene in Synthesis Example 1-1, and increasing the amount of water for extraction.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US08105748B2uspto-grants-2012_01