تفاعل #459331

ord-727b2482d36e478abf15a26d4c678235

معادلة التفاعل

CCC(=O)O
propionic acid
[Na]
sodium
CC(C)(C)[N+](C(C)(C)C)(C(C)(C)C)C(C)(C)C.CC(C)(C)[N+](C(C)(C)C)(C(C)(C)C)C(C)(C)C.O=S(=O)([O-])[O-]
tetra-t-butylammonium sulfate
[K+].[OH-]
potassium hydroxide
COc1ccccc1
anisole
CC[P+](CC)(C(C)(C)C)C(C)(C)C.CC[P+](CC)(C(C)(C)C)C(C)(C)C.O=S(=O)([O-])[O-]
diethyldi-t-butylphosphonium sulfate
→
CCCOc1ccccc1OC
propoxyanisole
COc1ccccc1
anisole

المتفاعلات

CCC(=O)O
propionic acid
[Na]
sodium
CC(C)(C)[N+](C(C)(C)C)(C(C)(C)C)C(C)(C)C.CC(C)(C)[N+](C(C)(C)C)(C(C)(C)C)C(C)(C)C.O=S(=O)([O-])[O-]
tetra-t-butylammonium sulfate
[K+].[OH-]
potassium hydroxide
—
graphite
COc1ccccc1
anisole
—
stainless steel
CC[P+](CC)(C(C)(C)C)C(C)(C)C.CC[P+](CC)(C(C)(C)C)C(C)(C)C.O=S(=O)([O-])[O-]
diethyldi-t-butylphosphonium sulfate

الكواشف

[Pt]
platinum
CC[P+](CC)(CC)CC.[Cl-]
tetraethylphosphonium chloride

المذيبات

O
water

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    أخرىhereinbefore set forth may produce similar

الإجراء التجريبي

The treatment of anisole with propionic acid, sodium or potassium hydroxide, water and other phase transfer agents such as tetra-t-butylammonium sulfate, tetraethylphosphonium chloride, diethyldi-t-butylphosphonium sulfate, etc., in an electrochemical cell utilizing platinum anodes and stainless steel or graphite cathodes and utilizing electrical energy within the range hereinbefore set forth may produce similar results in the conversion of anisole to propoxyanisole.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US04089757uspto-grants-1978_05