تفاعل #42774

ord-d432949c0c7046e1843b5cf1467f7cf1

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    غسيلwashed with water (3×100 ml) and saturated brine (50 ml)
  2. 2
    تجفيفdried (MgSO4)
  3. 3
    ترشيحfiltered
  4. 4
    أخرىthe filtrate is evaporated
  5. 5
    أخرىto give a pale pink solid

الإجراء التجريبي

3-(4-Chlorophenyl)-7-hydroxy-2-isopropyl-chromen-4-one (2.3 g, 7.31 mmol) is suspended in dry dichloromethane (140 ml) at room temperature. N-iodosuccinimide (1.73 g, 7.67 mmol) is added, and the mixture is stirred vigorously at room temperature for 30 min. The mixture is diluted with dichloromethane (60 ml), washed with water (3×100 ml) and saturated brine (50 ml), dried (MgSO4) and filtered, and the filtrate is evaporated to give a pale pink solid.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US07732435B2uspto-grants-2010_06