تفاعل #417926

ord-00145c8c545a46f1a638a2987364c249

معادلة التفاعل

[Na+].[OH-]
sodium hydroxide
CCCCCC/C=C\CCCOc1ccc(C(=O)OC)cc1
33
CCCCCC/C=C\CCCOc1ccc(C(=O)OC)cc1
methyl 4-(undec-4Z-enyloxy)benzoate
CCCCCC/C=C\CCCOc1ccc(C(=O)O)cc1
white solid
المردود 98.1%
CCCCCC/C=C\CCCOc1ccc(C(=O)O)cc1
4-(undec-4Z-enyloxy)benzoic acid
المردود 98.1%

الكواشف

لا شيء

المذيبات

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    درجة الحرارةThe solution is refluxed for 20 hours
  2. 2
    أخرىAfter evaporating off the solvent
  3. 3
    استخلاصextracted with DCM

الإجراء التجريبي

550 μL of 1 N sodium hydroxide solution (550 μmol) are added portionwise to 109 mg of 33 (358 μmol) in methanol (4 mL). The solution is refluxed for 20 hours. After evaporating off the solvent, the reaction medium is acidified with 0.5 N HCl and extracted with DCM. 102 mg of a white solid are obtained, i.e. a yield of 98%.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US08877684B2uspto-grants-2014_11