تفاعل #4045
ord-a2d4c15aa91b4bc49e43d3bde49780ee
معادلة التفاعل
perfluoro-2-methyl-3-oxahexanoyl fluoride
sodium trimethylsilanolate
→
Sodium perfluoro-2-methyl-3-oxahexanoate
المردود 69.3%
الكواشف
لا شيء
المذيبات
ظروف التفاعل
الظروف التفصيلية
See reaction.notes.procedure_details.
المعالجة
- 1أخرىa 2 h reaction time
الإجراء التجريبي
The procedure of Example 1 was followed using perfluoro-2-methyl-3-oxahexanoyl fluoride (16.6 g, 50 mmol), sodium trimethylsilanolate (5.6 g, 50 mmol), and dry tetrahydrofuran (100 mL), and a 2 h reaction time. Sodium perfluoro-2-methyl-3-oxahexanoate (12.2 g, 69% yield) was isolated as a white solid: The 19F NMR data were the same as reported in Example 15.