تفاعل #3844

ord-f05182efc7494917864a6ea459070b88

معادلة التفاعل

N
ammonia
O=P([O-])([O-])[O-].O=P([O-])([O-])[O-].O=P([O-])([O-])[O-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[F-]
phosphate rock
O=P(O)(O)O
phosphoric acid
O=S(=O)(O)O
sulfuric acid
→
O=P12OP3(=O)OP(=O)(O1)OP(=O)(O2)O3
P2O5

المتفاعلات

N
ammonia
O=P([O-])([O-])[O-].O=P([O-])([O-])[O-].O=P([O-])([O-])[O-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[F-]
phosphate rock
O=P(O)(O)O
phosphoric acid
O=S(=O)(O)O
sulfuric acid

الكواشف

لا شيء

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

الإجراء التجريبي

In 1970, Richmond et al ('641 supra) reacted phosphate rock with phosphoric acid and then with sulfuric acid. The resulting acidulate was subsequently neutralized with anhydrous ammonia to produce a 7-21-0 (N--P2O5 --K2O) grade slurrey fertilizer. In later investigations Pottgiesser et al ('162 supra) produced a 13.5-6-0 (N--P2O5K2O) grade slurry by reacting nitric acid with phosphate rock and subsequently feeding the resulting slurry into a body of preneutralized solution maintained at pH 7-10 by addition thereto of aqua ammonia.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: USH0000425uspto-grants-1988_02