تفاعل #355253

ord-2185f00a59a84529b296bfcd938657d4

معادلة التفاعل

N#Cc1ccccc1C=O
2-cyanobenzaldehyde
O=C1CCCC(=O)C1
cyclohexane-1,3-dione
CCOC(=O)CC(=N)N
amidinoacetic acid ethyl ester
CCOC(=O)C1=C(N)NC2=C(C(=O)CCC2)C1c1ccccc1C#N
2-amino-4-(2-cyanophenyl)-1,4,5,6,7,8-hexahydro-5-oxoquinoline-3-carboxylic acid ethyl ester
المردود 49.0%

المذيبات

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

الإجراء التجريبي

Upon heating a solution of 6.5 g of 2-cyanobenzaldehyde, 5.6 g of cyclohexane-1,3-dione and 6.5 g of amidinoacetic acid ethyl ester in 100 ml of ethanol for 5 hours, 2-amino-4-(2-cyanophenyl)-1,4,5,6,7,8-hexahydro-5-oxoquinoline-3-carboxylic acid ethyl ester of melting point 165°C (ethanol) is obtained.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US03946026uspto-grants-1976_03