تفاعل #350549

ord-d7990f7b93cc4b68a753a37835072594

معادلة التفاعل

c1ccncc1
Pyridine
CCCCCl
n-butyl chloride
C1COCCO1
dioxane
CCCC[n+]1ccccc1.[Cl-]
butylpyridinium chloride

الكواشف

لا شيء

المذيبات

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    درجة الحرارةcooled
  2. 2
    أخرىprecipitating the crystals
  3. 3
    أخرىformed

الإجراء التجريبي

Pyridine and excess n-butyl chloride were heated under reflux in nitromethane for 24 hours and then cooled, and the reaction solution was poured into dioxane, thereby precipitating the crystals formed. Thus, crude crystals of butylpyridinium chloride (BPC) were obtained. These were purified by recrystallizing them in methanol/dioxane solvent two or three times and then fully dried in vacuum.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US05643490uspto-grants-1997_07