تفاعل #318161

ord-857f034ffc68496fba840bb435b2c79a

معادلة التفاعل

CC(C=CC1=C(C)CCCC1(C)C)=CC=CC(C)=CCOC=O
retinyl esters
CC1=C(/C=C/C(C)=C/C=C/C(C)=C/CO)C(C)(C)CCC1
all-trans-retinol
CC1=C(/C=C/C(C)=C/C=C\C(C)=C\CO)C(C)(C)CCC1
11-cis-retinol
O[C@H](CS)[C@H](O)CS
dithiothreitol
NC(CO)(CO)CO
Tris
CC1=C(/C=C/C(C)=C/C=C/C(C)=C/CO)C(C)(C)CCC1
all-trans-retinol
CC1=C(/C=C/C(C)=C/C=C\C(C)=C\CO)C(C)(C)CCC1
11-cis-retinol
CCCCCCCCCCCCCCCC(=O)OC[C@H](COP(=O)([O-])OCC[N+](C)(C)C)OC(=O)CCCCCCCCCCCCCCC
DPPC
CCCCCCCCCCCCCCCC(=O)OC/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CCCC1(C)C
retinyl palmitate

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    أخرىAfter 10 min the reaction was quenched with 500 μL methanol, 100 μL of water and 500 μL of hexane

الإجراء التجريبي

Isomeric preference of the mRPE65/tLRAT mediated esterification of retinols: The effect of mRPE65 on the processing of 11-cis-and all-trans-retinols was determined by monitoring the formation of tLRAT catalyzed retinyl esters from added all-trans-retinol [11,12-3H2], 11-cis-retinol [15-3H] and mRPE65. The reaction mixture (volume 0.1 mL) contains 100 mM Tris (pH 8.4), 5 μM of tLRAT 0.3% CHAPS, 1 mM dithiothreitol and 0.2 μm of all-trans-retinol [11,12-3H2] or 11-cis-retinol [15-3H] and mRPE65 (0.02 μM) or 200 μM/0.4% DPPC/BSA was incubated for 10 min at room temperature. After 10 min the reaction was quenched with 500 μL methanol, 100 μL of water and 500 μL of hexane. The amount of retinyl palmitate formed, as determined by normal phase-HPLC, was used as a measure of activity. Each experiment was done in triplicate, and the data points used are an average of these three points. The standard error was presented as error bars.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US07566808B2uspto-grants-2009_07