تفاعل #310778

ord-331af467cc32488fbe9b8e69b558ba30

معادلة التفاعل

O=S(=O)([O-])[O-].[Mg+2]
magnesium sulphate
O=P([O-])(O)O.[NH4+]
ammonium dihydrogen phosphate
O=P([O-])(O)O.[K+]
potassium dihydrogen phosphate
O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO
glucose
O=C([O-])[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO
gluconate
O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO
D-glucose
[Na+].[OH-]
sodium hydroxide
→
O=C([O-])[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.[Na+]
Sodium gluconate

المتفاعلات

—
sterile aqueous solution
O=S(=O)([O-])[O-].[Mg+2]
magnesium sulphate
O=P([O-])(O)O.[NH4+]
ammonium dihydrogen phosphate
O=P([O-])(O)O.[K+]
potassium dihydrogen phosphate
O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO
glucose
O=C([O-])[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO
gluconate
O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO
D-glucose
[Na+].[OH-]
sodium hydroxide

الكواشف

لا شيء

المذيبات

O
H2O

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    أخرىis inoculated, in a fermenter, with a shaken culture of Acetobacter suboxydans ATCC 621 at a temperature of 30° C.
  2. 2
    درجة الحرارةA pH value of 5.5-6.0 is maintained
  3. 3
    درجة الحرارةthe mixture is cooled

الإجراء التجريبي

10 l of a sterile aqueous solution which contains 1.5 kg of D-glucose.H2O, 10 g of dry corn steep nutrient, 10 g of ammonium dihydrogen phosphate, 10 g of potassium dihydrogen phosphate and 5 g of magnesium sulphate, and which has a pH value of 6.5, is inoculated, in a fermenter, with a shaken culture of Acetobacter suboxydans ATCC 621 at a temperature of 30° C., and the mixture is aerated, while stirring. A pH value of 5.5-6.0 is maintained by metering in sodium hydroxide solution. After about 40 hours, when all of the glucose has been converted to gluconate, the mixture is cooled and centrifuged. Sodium gluconate can be obtained in crystalline form in a yield of over 90% by evaporating the centrifuged solution.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US04355158uspto-grants-1982_10