تفاعل #2467914
ord-fe37518752c5466fb37b10ca595fe018
معادلة التفاعل
2,3,5-Triiodobenzoyl chloride
1-(z,z,z-octadeca-6,9,12-trienoyloxy)-3-hydroxypropane
triethylamine
→
1-(2,3,5-triiodobenzoyloxy)-3-(z,z,z-octadeca-6,9,12-trienoyloxy) propane
المتفاعلات
الكواشف
لا شيء
المذيبات
ظروف التفاعل
الظروف التفصيلية
See reaction.notes.procedure_details.
المعالجة
- 1تركيزThe mixture was concentrated
- 2أخرىpurified by flash chromatography (ethyl acetate/hexane)
الإجراء التجريبي
2,3,5-Triiodobenzoyl chloride (1.54 g, 3.08 mmol) was added to a mixture of 1-(z,z,z-octadeca-6,9,12-trienoyloxy)-3-hydroxypropane (1 g, 2.97 mmol) and triethylamine (1 ml) in methylene chloride (80 ml) and the resulting mixture stirred overnight at room temperature under nitrogen. The mixture was concentrated and purified by flash chromatography (ethyl acetate/hexane) to yield 1-(2,3,5-triiodobenzoyloxy)-3-(z,z,z-octadeca-6,9,12-trienoyloxy) propane.