تفاعل #2267055

ord-1a1a3434cae245c49c2a39443e27ee10

معادلة التفاعل

O=S(=O)(Cl)c1c(F)c(F)c(F)c(F)c1F
pentafluorobenzenesulfonyl chloride
C[N+](C)(C)C.[OH-]
tetramethylammonium hydroxide
C[N+](C)(C)C.O=S(=O)([O-])c1c(F)c(F)c(F)c(F)c1F
tetramethylammonium pentafluorobenzenesulfonate

المذيبات

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    درجة الحرارةcooling

الإجراء التجريبي

25 gof pentafluorobenzenesulfonyl chloride was dissolved in 100 ml of methanol under ice-cooling. Then 100 g of a 25% aqueous solution of tetramethylammonium hydroxide was slowly added thereto. By stirring at room temperature for 3 hours, a solution of tetramethylammonium pentafluorobenzenesulfonate was obtained. Thus solution was employed in salt exchange between sulfonium salt and iodonium salt.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US06887645B2uspto-grants-2005_05