تفاعل #2204031
ord-bfc578e8e6f64046a7b6059121fa75f3
معادلة التفاعل
الكواشف
لا شيء
ظروف التفاعل
الظروف التفصيلية
See reaction.notes.procedure_details.
المعالجة
- 1درجة الحرارةcooling
- 2ترشيحThe residue is filtered off
- 3غسيلwashed with 10 ml of ice-water
- 4أخرىsubsequently dried at 50° C. under reduced pressure (7.0 Pa)
الإجراء التجريبي
3.60 g of sodium perchlorate in 10 ml of water are added with stirring to a solution of 5.00 g (29.2 mmol) of bis(dimethylamino)dichloromethane in 20 ml of water. The reaction mixture is subsequently stirred for 1 hour with ice-cooling. The residue is filtered off and washed with 10 ml of ice-water and subsequently dried at 50° C. under reduced pressure (7.0 Pa), giving 6.64 g of bis(dimethylamino)chlorocarbenium perchlorate, corresponding to a yield of 94.0%.