تفاعل #2200632

ord-386e2d333884458d94b5dc6865bb9298

معادلة التفاعل

Cc1cn(-c2ccc(Cl)cc2C#N)cn1
5-chloro-2-(4-methyl-imidazol-1-yl)-benzonitrile
C=[N+](C)C.[I-]
Eschenmoser's salt
Cc1ncn(-c2ccc(Cl)cc2C#N)c1CN(C)C
title compound
المردود 17.0%
Cc1ncn(-c2ccc(Cl)cc2C#N)c1CN(C)C
5-Chloro-2-(5-dimethylaminomethyl-4-methyl-imidazol-1-yl)-benzonitrile
المردود 17.0%

الكواشف

لا شيء

المذيبات

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    أخرىEvaporation of the solvent, aqueous workup and crystallization from Ethyl acetate

الإجراء التجريبي

In analogy to example 5b, 5-chloro-2-(4-methyl-imidazol-1-yl)-benzonitrile was reacted with Eschenmoser's salt in DMF for 16 h at 90° C. Evaporation of the solvent, aqueous workup and crystallization from Ethyl acetate afforded the title compound as a white solid (yield: 17%). MS: m/e=275.1 [M+H]+.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US07432256B2uspto-grants-2008_10