تفاعل #2200580

ord-0a4f8565419647198ba9e76e9bf2d4d4

معادلة التفاعل

CCOC(=O)[C@@H](C)[C@H](C)OC1CCCCO1
ethyl (2S,3S)-2-methyl-3-tetrahydropyranyloxybutanoate
[Al+3].[H-].[H-].[H-].[H-].[Li+]
LiAlH4
[Na+].[OH-]
NaOH
C[C@H](CO)[C@H](C)OC1CCCCO1
(2R,3S)-2-methyl-3-tetrahydropyranyloxybutanol

المذيبات

ظروف التفاعل

درجة الحرارة
0°CELSIUS
الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    workup.WAITat room temperature for 30 minutes
  2. 2
    workup.ADDITIONthe reaction was treated
  3. 3
    workup.STIRRINGAfter having stirred for at least 30 minutes
  4. 4
    ترشيحthe mixture is filtered on Celite
  5. 5
    غسيلThe precipitated aluminum salts were then washed with EtOAc
  6. 6
    أخرىThe solvent was evaporated
  7. 7
    أخرىthe residual oil was purified by means of flash chromatography on a silica gel column (heptane/EtOAc=5:1

الإجراء التجريبي

A solution of ethyl (2S,3S)-2-methyl-3-tetrahydropyranyloxybutanoate (4) (8.18 g, 35.56 mmol) at 0° C. was added dropwise to a stirred suspension of LiAlH4 (2.70 g, 71.12 mmol) in THF/toluene (2:1) (178 ml). The reaction mixture is stirred at 0° C. for 30 minutes, and then at room temperature for 30 minutes. The reaction is neutralized by means of the “Fieser treatment”; the reaction was treated by successively adding dropwise 2.7 ml of ice-cold water, 2.7 ml of a 15% aqueous NaOH solution, and 3×2.7 ml of ice-cold water. After having stirred for at least 30 minutes, the mixture is filtered on Celite. The precipitated aluminum salts were then washed with EtOAc. The solvent was evaporated, the residual oil was purified by means of flash chromatography on a silica gel column (heptane/EtOAc=5:1 and then 2:1) in order to obtain (2R,3S)-2-methyl-3-tetrahydropyranyloxybutanol (5) in the form of a colorless oil (6.59 g, 99%): 1H NMR (250 MHz, CDCl3) δ 4.69 to 4.67 (m, 0.5H); 4.58 to 4.56 (m, 0.5H); 3.98 to 3.43 (m, 5H); 1.80 to 1.48 (m, 7H); 1.29 (d, J=6.3 Hz, 1.5H); 1.18 (d, J=6.1 Hz, 1.5H); 0.95 (d, J=7.0 Hz, 1.5H); 0.94 (d, J=7.0 Hz, 1.5H); 13C NMR (50 MHz, CDCl3) δ 99.9; 97.4; 78.4; 74.9; 65.2; 64.2; 62.7; 41.2; 40.6; 31.3; 31.0; 25.3; 25.1; 20.7; 19.8; 18.9; 17.5; 14.0; 13.0; MS (CI) m/z 189 [M+H]+. HRMS calculated for C10H21O3 (M+H), 189.14906; found, 189.14755.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US07432087B2uspto-grants-2008_10