تفاعل #216833

ord-6384164cd22146bd8e8ee6bce72735ff

معادلة التفاعل

[Cl-].c1ccc([I+]c2ccccc2)cc1
diphenyliodonium chloride
Fc1c(F)c(F)c([B-](c2c(F)c(F)c(F)c(F)c2F)(c2c(F)c(F)c(F)c(F)c2F)c2c(F)c(F)c(F)c(F)c2F)c(F)c1F.[Li+]
lithium tetrakis(pentafluorophenyl)borate
Fc1c(F)c(F)c([B-](c2c(F)c(F)c(F)c(F)c2F)(c2c(F)c(F)c(F)c(F)c2F)c2c(F)c(F)c(F)c(F)c2F)c(F)c1F.c1ccc([I+]c2ccccc2)cc1
diphenyliodonium tetrakis(pentafluorophenyl)borate
المردود 75.0%

الكواشف

لا شيء

المذيبات

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    درجة الحرارةThe mixture was maintained
  2. 2
    ترشيحwas then filtered
  3. 3
    أخرىThe filtrate was dried under reduced pressure (133 Pa) overnight with the exclusion of light
  4. 4
    أخرى16.33 g (or a yield of 75%) of diphenyliodonium tetrakis(pentafluorophenyl)borate were thus recovered

الإجراء التجريبي

7.17 g (or 22.6 mmol) of diphenyliodonium chloride were dissolved in 300 ml of water in a 1,000 ml Erlenmeyer flask. 15.52 g (or 22.6 mmol) of lithium tetrakis(pentafluorophenyl)borate in solution in 250 ml of water were added dropwise. The mixture was maintained under stirring for 30 minutes and was then filtered. The filtrate was dried under reduced pressure (133 Pa) overnight with the exclusion of light. 16.33 g (or a yield of 75%) of diphenyliodonium tetrakis(pentafluorophenyl)borate were thus recovered.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US05468902uspto-grants-1995_11