تفاعل #2146716

ord-d5d21783bbe942d097f1788700f51f1a

معادلة التفاعل

C1=C2CC(=C1)c1ccccc12
benzonorbornadiene
c1ccoc1
furan
c1ccc2cc3cc4cc5ccccc5cc4cc3cc2c1
pentacene
المردود 40.0%

الكواشف

لا شيء

ظروف التفاعل

درجة الحرارة
128°CELSIUS
الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    أخرىto produce pentacene in nearly quantitative yield

الإجراء التجريبي

In summary, a new stable and soluble pentacene precursor 2 was synthesized in 40% yield from the cycloaddition of a furan derivative 3 and a benzonorbornadiene 4. Compound 2 releases a unit of CO upon heating at 128° C. or by irradiation with UV light (366 nm) to produce pentacene in nearly quantitative yield. Thin films of pentacene were prepared by spin-coating followed by thermal annealing, and found to display typical FET characteristics.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US08277903B2uspto-grants-2012_10