تفاعل #2146716
ord-d5d21783bbe942d097f1788700f51f1a
معادلة التفاعل
benzonorbornadiene
furan
→
pentacene
المردود 40.0%
المتفاعلات
الكواشف
لا شيء
ظروف التفاعل
درجة الحرارة
128°CELSIUS
الظروف التفصيلية
See reaction.notes.procedure_details.
المعالجة
- 1أخرىto produce pentacene in nearly quantitative yield
الإجراء التجريبي
In summary, a new stable and soluble pentacene precursor 2 was synthesized in 40% yield from the cycloaddition of a furan derivative 3 and a benzonorbornadiene 4. Compound 2 releases a unit of CO upon heating at 128° C. or by irradiation with UV light (366 nm) to produce pentacene in nearly quantitative yield. Thin films of pentacene were prepared by spin-coating followed by thermal annealing, and found to display typical FET characteristics.