تفاعل #1985944

ord-cf38f96581534566aa8c89c9a242ad2a

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    غسيلthe organic layer washed with water, brine
  2. 2
    تجفيفdried over magnesium sulfate
  3. 3
    ترشيحfiltered
  4. 4
    تركيزconcentrated in vacuo

الإجراء التجريبي

To a solution of methyl 5-acetoxy-2-formyl-4-methoxyhydrocinnamate (3.31 g) and imidazole (2.42 g) in methylene chloride (25 ml) is added a solution of tert-butylchlorodimethylsilane (2.73 g) in methylene chloride (25 ml). The mixture is stirred at room temperature for about 60 minutes, diluted with ether and water, and the organic layer washed with water, brine, dried over magnesium sulfate, filtered and concentrated in vacuo to give the desired product.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US05571506uspto-grants-1996_11