تفاعل #1980285

معادلة التفاعل

carbazole

1,4-dibromonaphthalene

diaminohexane

K3PO4

→

title compound

المردود 6.0%

4′-naphthyl-3,6-diphenylcarbazole

المردود 6.0%

المذيبات

dioxane

ظروف التفاعل

المعالجة

1. 1
   أخرىAs depicted in Reaction 6
2. 2
   أخرىAfter completion of the reaction
3. 3
   استخلاصthe reaction mixture was extracted with ethyl acetate
4. 4
   أخرىAfter the solvent was removed under reduced pressure
5. 5
   أخرىthe residue was purified by column chromatography

الإجراء التجريبي

As depicted in Reaction 6, a solution of 10 g (31.3 mmol) of carbazole, 13.5 g (31.3 mmol) of 1,4-dibromonaphthalene, CuI, diaminohexane and K3PO4 in dioxane was refluxed for 15 hours. After completion of the reaction, the reaction mixture was extracted with ethyl acetate. After the solvent was removed under reduced pressure, the residue was purified by column chromatography to give the title compound. The product was collected by filtration under reduced pressure and dried. Yield: 6%. MS (EI) (Calcd. for C34H22BrN: 523.09. Found: 523).

المصدر