تفاعل #1929055

ord-4e127cdbee584fd48a1f74d53939a02e

معادلة التفاعل

COC(=O)CCCCCCCCCCCCCCCN=[N+]=[N-]
16-azidohexadecanoic acid methyl ester
COC(=O)CCCCCCCCCCCCCCCN
amine
COC(=O)CCCCCCCCCCCCCCCN
16-aminohexadecanoic acid methyl ester

الكواشف

المذيبات

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

الإجراء التجريبي

16-azidohexadecanoic acid methyl ester is catalytically hydrogenated with palladium/activated charcoal in methanol at 3 bar for three hours to give the corresponding amine (Zinic et al., Positionally Isomeric Organic Gelators: Structure-Gelation Study, Racemic versus Enantiomeric Gelators, and Solvation Effects, Chem. Eur. J. 2010; 16:3066-82).

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US08945897B2uspto-grants-2015_02