تفاعل #1929032

معادلة التفاعل

sodium dichromate dihydrate

ether

1-bromo-2-dodecanol

→

1-bromo-2-dodecanone

المردود 80.0%

المذيبات

water

sulfuric acid

acetone

ظروف التفاعل

المعالجة

1. 1
   أخرىA solution obtained in advance
2. 2
   workup.ADDITIONwas dropped
3. 3
   أخرىthe solvent was removed
4. 4
   أخرىAs a result, a white solid was obtained

الإجراء التجريبي

In a 1000 ml eggplant-shaped flask, 14 g of 1-bromo-2-dodecanol was dissolved in 110 ml of acetone. A solution obtained in advance by dissolving 35 g of sodium dichromate dihydrate in 150 ml of distilled water and 25 ml of sulfuric acid was dropped thereto. These substances were stirred at room temperature for 1.5 hours, and then 250 ml of ether was added thereto. The resultant substance was dehydrated, and the solvent was removed. As a result, a white solid was obtained. The yield was 80%.

المصدر