تفاعل #1912875

ord-e2b222811baf4d4a886cc0be4c38af81

معادلة التفاعل

CC(C)(C)NCC(O)c1ccc(O)c(CO)c1.O=S(=O)(O)O
albuterol sulfate
CCCCCCCCCCCCCCCC(=O)OC[C@H](COP(=O)([O-])OCC[N+](C)(C)C)OC(=O)CCCCCCCCCCCCCCC
DPPC
CC(C)(C)NCC(O)c1ccc(O)c(CO)c1.O=S(=O)(O)O
albuterol sulfate
CCO.O
ethanol water
CC(C)(C)NCC(O)c1ccc(O)c(CO)c1.O=S(=O)(O)O
albuterol sulfate
CC(C)(C)NCC(O)c1ccc(O)c(CO)c1
Albuterol

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    أخرىwere prepared
  2. 2
    أخرىPre-spray drying solutions
  3. 3
    أخرىwere prepared
  4. 4
    تركيزFinal total solute concentration of the solution
  5. 5
    أخرىdrying
  6. 6
    أخرىwas prepared
  7. 7
    workup.ADDITIONmixing the two solutions
  8. 8
    أخرىto yield one liter of cosolvent with a total solute concentration of 1 g/L (w/v)
  9. 9
    تركيزHigher solute concentrations of 3 g/L (w/v)
  10. 10
    أخرىwere prepared
  11. 11
    أخرىThe solution was spray-dried
  12. 12
    workup.ADDITIONcontaining formulation
  13. 13
    أخرىwas from about 110° C. to about 140° C.
  14. 14
    أخرىranged from about 45–57° C.

الإجراء التجريبي

The albuterol sulfate powder formulations listed in Table 7, were prepared as follows. Pre-spray drying solutions were prepared by dissolving the lipid in ethanol and albuterol sulfate and leucine in water. The ethanol solution was then mixed with the water solution at a ratio of 70/30 ethanol/water. Final total solute concentration of the solution used for spray drying varied from 1 g/L to 3 g/L. As an example, the DPPC/leucine/albuterol sulfate (76/16/8) spray drying solution was prepared by dissolving 760 mg of DPPC in 700 mL of ethanol, dissolving 160 mg leucine and 870 mg of albuterol sulfate in 300 mL water and then mixing the two solutions to yield one liter of cosolvent with a total solute concentration of 1 g/L (w/v). Higher solute concentrations of 3 g/L (w/v) were prepared by dissolving three times more of each solute in the same volumes of ethnaol and water. The solution was spray-dried as described above for the insulin containing formulation. Specifically, the inlet temperature was from about 110° C. to about 140° C., and the outlet temperature ranged from about 45–57° C.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US07048908B2uspto-grants-2006_05