تفاعل #1904029

ord-d2aaa3eec09140fa93094b25d13f386a

المذيبات

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    ترشيحThe solution was filtered through kieselguhr
  2. 2
    تركيزconcentrated in vacuo

الإجراء التجريبي

3-(methoxycarbonylmethylene)glutaric acid dimethylester (89 g, 267 mmol) in methanol (200 ml) was shaken with (10% palladium on charcoal: 50% water) (9 g) under an atmosphere of hydrogen gas (3.5 bar) for (30 h). The solution was filtered through kieselguhr and concentrated in vacuo to give 3-(methoxycarbonylmethyl)glutaric acid dimethylester as an oil, yield (84.9 g, 94%).

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US07597875B2uspto-grants-2009_10